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(Single layer of carbon atoms "torn" out with tape graphene and graphene oxide)
When discussing graphene, we need to first state the all-natural mineral graphite that is widely present in our day-to-day live.
As an allotrope of carbon, graphite is a split material, and the carbon atoms inside graphite are prepared layer by layer. Carbon atoms in the very same layer “hold hands” and are closely attached, yet the combination of carbon atoms between various layers is loose, like a pile of playing cards. With a gentle press, the cards will certainly move apart.
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From the perspective of chemical structure, graphite is a transitional crystal in between atomic crystals, metal crystals and molecular crystals. In the crystal, carbon atoms in the very same layer type covalent bonds with sp2 hybridization, each carbon atom is attached to 3 various other carbon atoms, and six carbon atoms develop a routine hexagonal ring on the very same aircraft, stretching to create a sheet framework.
If graphite is a stack of playing cards, after that graphene is just one of the cards in this stack of playing cards. Graphene is a two-dimensional product made up of a solitary layer of carbon atoms. Piling graphene layer by layer is graphite. A 1 mm thick graphite consists of regarding 3 million layers of graphene.
Although graphene exists in nature, it is hard to peel off a solitary layer framework.
Greater than twenty years ago, Andre Geim and Konstantin Novoselov, researchers at the College of Manchester in the UK, believed that there need to be a means to obtain a solitary layer of graphite.
Exactly how can a single layer of graphite be peeled off? Researchers took a very “straightforward and unrefined” method – sticking it with tape.
“Similar to when we compose a typo theoretically, we will certainly stick the typo with tape.” Based on this, scientists boldly connect that if tape can stick to the surface of paper, can it also adhere to layers of graphite?
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In the experiment, researchers stuck both sides of pyrolytic graphite flakes to a special tape, and tore off the tape, the graphite sheet was split into 2. Although the thickness of graphite currently is still far from that of a single layer of graphite, researchers have validated the expediency of this method – each time the tape is utilized, the graphite comes to be thinner. By demanding utilizing this “mechanical exfoliation technique” to repeat the operation, they lastly got a slim sheet containing only one layer of carbon atoms, which is graphene.
Nevertheless, this approach of repeatedly scrubing graphite sheets with tape to obtain graphene has low production effectiveness and can just be used to prepare micron-thick graphene, and can not be mass-produced industrially.
Later, with the renovation of clinical and technological levels, the preparation technique of graphene has additionally made excellent development. Presently, along with this traditional physical and mechanical exfoliation technique, there are likewise several techniques for preparing graphene, such as redox technique, solvent exfoliation method, chemical vapor deposition, etc
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(Single layer of carbon atoms "torn" out with tape graphene and graphene oxide)





